articleJournal of the American Chemical SocietyMay 23, 2025Closed access

Establishing Dual-Interface Built-In Electric Fields within Janus Heterostructures for Cooperative Photoredox Catalysis

University of Science and Technology of China · National University of Singapore · +3 more institutions

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Abstract

Rationally designing nanostructures and comprehensively understanding the structure–property relationships are important for directional charge transfer. A general dual-interface built-in electric field (BIEF) regulation strategy is developed to synthesize the bifunctional ZnS/Sv-chalcogenide/Ti3C2 heterostructure photocatalysts (Sv represents sulfur vacancies; chalcogenides include ZnIn2S4, CdS, and CdIn2S4) consisting of a ZnS/chalcogenide S-scheme heterojunction and a Sv-chalcogenide/Ti3C2 Schottky heterojunction. The ternary-component photocatalyst construction involves hollow core–shell heterostructure establishment via lateral epitaxy and chalcogenide-surface Ti3C2 nanoparticle introduction via a…

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