reviewChemical Society ReviewsJan 1, 2025HYBRID OA

Chemical engineering of zeolites: alleviating transport limitations through hierarchical design and shaping

King Abdullah University of Science and Technology · University of Alicante

PubMed
Indexed incrossrefpubmed

Abstract

Zeolites are indispensable catalysts in a wide range of industrial applications due to their well-defined microporous structures and exceptional shape-selective properties. However, their practical use is often constrained by diffusion limitations, which can hinder reactant accessibility, influence product selectivity, and accelerate catalyst deactivation. This review critically examines strategies to alleviate these diffusion constraints, focusing on hierarchical structuring, nanozeolite synthesis, and advanced shaping techniques. We discuss fundamental diffusion theories, experimental characterization methods, and emerging methodologies that enhance mass transport in zeolites. By bridging fundamental…

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