Configurational entropy-tailored NASICON cathode redox chemistry for capacity-dense and ultralong cyclability

Zhang, Wei; He, Liang; Li, Jiantao; Yu, Ruohan; Xu, Zhenming; Wu, Yulun; Qu, Haotian; Zhang, Qi; Li, Jianwei; Wu, Xian; Fu, Qingjin; Lai, Yanqing; Zhou, Guangmin; He, Guanjie; Parkin, Ivan P.

doi:10.1039/d5ee00877h

articleEnergy & Environmental ScienceJan 1, 2025HYBRID OA

Configurational entropy-tailored NASICON cathode redox chemistry for capacity-dense and ultralong cyclability

WZWei Zhang LHLiang He JLJiantao Li RYRuohan Yu ZXZhenming Xu

University Town of Shenzhen · Tsinghua–Berkeley Shenzhen Institute · +5 more institutions

Indexed incrossref

Abstract

High-entropy engineering is applied to NASICON-type cathodes to overcome long-standing trade-offs between structural stability and electrochemical performance, enabling high capacity, exceptional rate capability, and long-term cycling durability.

Citation impact

total citations

FWCI: 17.85
Percentile: 100%
References: 68

Citations per year

Authors

WZ
Wei ZhangCorresponding
University Town of Shenzhen, Tsinghua–Berkeley Shenzhen Institute, University College London
LH
Liang He
Central South University
JL
Jiantao Li
Northwestern University, University College London
RY
Ruohan Yu
Sanya University
ZX
Zhenming Xu
Nanjing University of Aeronautics and Astronautics

Topics & keywords

Topics

Machine Learning in Materials Science100%
Catalysis and Oxidation Reactions99%
Electrochemical Analysis and Applications99%

Keywords

Redox
Cathode
Fast ion conductor
Chemical engineering
Materials science
Chemistry
Inorganic chemistry
Physical chemistry

No related works found for this paper.

Funding

UD
U.S. Department of Energy
Awards: AC02-06CH11357, DE-AC02, 06CH11357, DE-AC02-06CH11357, DE-AC02-
GO
Government of the United Kingdom
UR
UK Research and Innovation
Awards: EP/Y008707/1, 101077226
RS
Royal Society
Awards: IEC/NSFC/201261, RGS/R1/211080
NN
National Natural Science Foundation of China
Awards: 201261, DE-AC02-06CH11357
NU
Nanjing University of Aeronautics and Astronautics
WU
Wuhan University
WU
Wuhan University of Technology
Awards: 2020III002GX, 2019III012GX
NU
Nanjing University
SK
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing
SK
State Key Laboratory of Silicate Materials for Architectures
Award: SYSJJ2020-04
SB
STFC Batteries Network
Award: ST/R006873/1
OO
Office of Science
Awards: DE-AC02-06CH11357, DE-AC02, 06CH11357, AC02-06CH11357
HE
HORIZON EUROPE Framework Programme
EA
Engineering and Physical Sciences Research Council
Awards: EP/L015862/1, 101077226, EP/Y008707/1, DE-AC02-06CH11357, EP/V027433/3
SA
Science and Technology Facilities Council
Award: ST/R006873/1
FR
Fundamental Research Funds for the Central Universities
Awards: 2019III012GX, 2020III002GX
AN
Argonne National Laboratory
Awards: DE-AC02, 06CH11357, AC02-06CH11357