articleAdvanced MaterialsJun 5, 2025Closed access

Universal Ion Migration Suppression Strategy Based on Supramolecular Host–Guest Interaction for High‐Performance Perovskite Solar Cells

Kunming University of Science and Technology · Chongqing University · +4 more institutions

PubMed
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Abstract

Abstract The migration of multiple chemical species is are main factor leading to the intrinsic instability of perovskite solar cells (PSCs). Herein, a universal ion migration suppression strategy is innovatively reported to stabilize multiple functional layers by simultaneously suppressing the migration of multiple mobile chemical species based on host–guest interaction via calixarene supramolecules. After incorporating 4‐tert‐butylcalix[8]arene (C8A), the interfacial defects are passivated, suppressing trap‐assisted nonradiative recombination. Moreover, the p‐doping of Spiro‐OMeTAD is facilitated, and the extraction and transport of holes are promoted for n‐i‐p regular PSCs. The C8A doped regular devices…

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61
total citations
FWCI
34.98
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100%
References
46
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Authors

12

Topics & keywords

Keywords
  • Materials science
  • Perovskite (structure)
  • Energy conversion efficiency
  • Optoelectronics
  • Doping
  • Nanotechnology
  • Photovoltaics
  • Chemical engineering
UN Sustainable Development Goals
  • Affordable and clean energy
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