articleInorganic Chemistry CommunicationsJul 2, 2025HYBRID OA

NiCu alloy nanoparticles encapsulated in nitrogen-doped carbon nanotubes for highly efficient acidic hydrogen evolution reaction

Energy Storage Systems (United States) · Pingdingshan University · +2 more institutions

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Abstract

The use of low-cost non-precious metals to replace platinum as electrocatalysts for the hydrogen evolution reaction (HER) holds great potential, but their efficiency and stability still face challenges. Here, we report a nitrogen-doped carbon nanotube (NCNT) supported NiCu-x (x = 0.5, 1, 2) electrocatalyst for the hydrogen evolution reaction (HER) under acidic conditions. By optimizing the atomic molar ratio of Ni/Cu alloy nanoparticles, the optimal NiCu-1 catalyst was obtained, featuring a thin carbon shell and uniformly distributed alloy nanoparticles, and exhibiting outstanding HER activity. The NiCu-1 catalyst requires only 42 mV overpotential to achieve a current density of 10 mA/cm 2 . Its high…

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