articleeScienceJul 18, 2025GOLD OA

Mutual stabilization of hybrid and inorganic perovskites for photovoltaics

Wuhan National Laboratory for Optoelectronics · Huazhong University of Science and Technology · +7 more institutions

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Abstract

Stabilizing black-phase formamidinium lead triiodide (FAPbI 3 ) is critical for high-performance perovskite solar cells (PSCs). We present a stabilization strategy utilizing co-evaporated cesium lead iodide (CsPbI 3 ) capping layers. Enabled by favorable crystal lattice matching, cubic-phase CsPbI 3 spontaneously forms on FAPbI 3 surfaces, establishing mutual phase stabilization with the underlying black-phase FAPbI 3 . When combined with ammonium salt interface modification, the CsPbI 3 interlayer effectively suppresses the ion (FA + and F-PEA + ) diffusion between the stacked perovskite layers. The FAPbI 3 /CsPbI 3 bilayer structured devices exhibited a certified record reverse-scanning power-conversion…

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