Intermolecular 1,2-difunctionalization of alkenes
Dalian Institute of Chemical Physics · Chinese Academy of Sciences · +5 more institutions
Abstract
Three different reaction modes. Firstly, metal species can add double bonds by employing transition metals; further coupling can then be followed to complete the difunctionalization. Another intriguing approach is that radicals add to the olefins and then are quenched in diverse ways. The ability to continuously introduce diverse functional groups is the most significant feature of this platform. The third mode is that the olefin is transformed into a cationic radical or anionic radical intermediate through single-electron transfer. This strategy is less developed and more novel, but has certain limitations. Driven by the innovation of synthetic chemistry strategies, the difunctionalization of olefins, which…
Citation impact
- FWCI
- 38.88
- Percentile
- 100%
- References
- 561
Authors
5- YWYuanrui Wang
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, University of Chinese Academy of Sciences
- ZBZhipeng Bao
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Leibniz Institute for Catalysis, Dalian National Laboratory for Clean Energy
- XMXu-Dong Mao
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Leibniz Institute for Catalysis, Dalian National Laboratory for Clean Energy
- MHMing Hou
Hangzhou Normal University, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Leibniz Institute for Catalysis, Dalian National Laboratory for Clean Energy
- XWXiao‐Feng WuCorresponding
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Nankai University, Leibniz Institute for Catalysis, Dalian National Laboratory for Clean Energy
Topics & keywords
- Olefin fiber
- Double bond
- Cationic polymerization
- Radical
- Intermolecular force
- Functional group
- Molecule