Magnetic Properties of Organic Materials

Genesis of the concept: intermolecular ferromagnetic spin exchange structural determinants of the chemical and magnetic properties of non-kekule molecules antiaromatic triplet ground state molecules - building blocks for organic magnets. Theory of exchange in organic systems: resonating valence bond theory and magnetic properties qualitative and quantitative predictions and measurements of singlet-triplet splittings in non-Kekule hydrocarbon diradicals and heteroatom derivatives. Exchange in small organic open-shell systems: conformational exchange modulation in trimethylenemethane-type biradicals use of dinitrenes as models for intramolecular exchange radical ion building blocks for organic magnetic materials…