articleNano-Micro LettersJan 4, 2026DIAMOND OA

W/V Dual-Atom Doping MoS2-Mediated Phase Transition for Efficient Polysulfide Adsorption/Conversion Kinetics in Lithium–Sulfur Battery

Macau University of Science and Technology · University of Macau · +3 more institutions

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Abstract

Abstract The dissolvable polysulfides and sluggish Li 2 S conversion kinetics are acknowledged as two significant challenges in the application lithium–sulfur (Li–S) batteries. Herein, we introduce a dual-doping strategy to modulate the electronic structure of MoS 2 , thereby obtaining a multifunctional catalyst that serves as an efficient sulfur host. The W/V dual single-atom-doped MoS 2 grown on carbon nanofibers (CMWVS) demonstrates a strong adsorption ability for lithium polysulfides, suppressing the shuttle effects. Additionally, the doping process also results in the phase transition from 2H-MoS 2 to 1T-MoS 2 and generates sufficient edge sulfur atoms, promoting the charge/electron transfer and enriching…

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