articleChemical ScienceJan 1, 2026DIAMOND OA

Converting natural biopolymers to sustainable bioplastics via structure engineering

National University of Singapore · Shanghai Jiao Tong University

PubMed
Indexed incrossrefdoajpubmed

Abstract

Sustainable bioplastics have attracted considerable attention as alternatives to conventional petroleum-based plastics in response to growing concerns about resource depletion and environmental pollution. Natural biopolymers, such as starch, cellulose, and chitin/chitosan, are emerging as promising candidates for bioplastic production due to their widespread availability and biodegradability. This review conducts a comprehensive examination of recent advances in polymer-level structural engineering of natural biopolymers into bioplastics, with a focus on strategies that introduce intermolecular interactions, including permanent covalent bonds, dynamic covalent linkages, and noncovalent interactions, to…

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