Base Metal Catalysis in Nitrene Transfer Reactions
Indian Institute of Science Education and Research Pune
Abstract
Leveraging base metal catalysis to transform small organic molecules by forging X-N bonds (X = C, N, P, S) through nitrene transfer reactions (NTRs) renders a robust and sustainable paradigm shift for preparing valuable amine building blocks. Over the last four decades, 3d metal-catalyzed NTRs have received significant attention in the field of organic synthesis. This review will thoroughly discuss the manipulation of various complexes of base metals, such as Mn, Fe, Co, Ni, and Cu, to control the reaction pathways for X-N bond formation using different nitrene precursors. This review will encompass exemplary, pioneering, and pertinent synthesis in this area and will comprehensively elucidate the mechanistic…
Citation impact
- FWCI
- 72.16
- Percentile
- 100%
- References
- 303
Authors
6- HKHillol Khatua
Indian Institute of Science Education and Research Pune
- AGAnogh Ghosh
Indian Institute of Science Education and Research Pune
- SDSubrata Das
Indian Institute of Science Education and Research Pune
- SPSima Patra
Indian Institute of Science Education and Research Pune
- SNSouvik Nandi
Indian Institute of Science Education and Research Pune
Topics & keywords
- Nitrene
- Chemoselectivity
- Catalysis
- Organic synthesis
- Base (topology)
- Amine gas treating
- Organic molecules
- Organic base