Regulating Interfacial Dynamic Self‐Adjusting Hydrophobic Layer via Cationic Molecular Structure for Ultra‐Stable Zinc Metal Anode
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Abstract
The structure of solution additives significantly affects the polarization and dendrite behavior of metal batteries. In this study, we propose, for the first time, the "hydrophilic-lipophilic balance (HLB) value-spatial configuration synergistic regulation" strategy by selecting cations with different structures as additives, successfully revealing the structure-activity relationship between additive structures and the stability of the anode interface adsorption layer. Among them, the butyltrimethylammonium chloride additive (ADD4), which has a low HLB value and a linear structure, exhibits the most stable interfacial structure. The stable hydrophobic region formed by its spontaneous aggregation and assembly…
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7Topics & keywords
Topics
Keywords
- Overpotential
- Adsorption
- Faraday efficiency
- Anode
- Cationic polymerization
- Microstructure
- Metal
- Dendrite (mathematics)
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