articleJournal of the American Chemical SocietyJan 22, 2026GREEN OA

Optimizing toward Discovery: AI-Driven Exploration of Lewis Acid–Base Catalysts for PET Glycolysis

University of Science and Technology of China · Hefei National Center for Physical Sciences at Nanoscale · +2 more institutions

PubMed
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Abstract

The depolymerization of polyethylene terephthalate (PET) through efficient chemical recycling remains a central challenge in plastic waste valorization, in part because the catalyst landscape is vast and sparsely explored. Here, we present an artificial intelligence (AI)-driven discovery framework that integrates Bayesian optimization (BO), large language models (LLMs), and high-throughput robotics to accelerate the search for Lewis acid–base catalysts for PET glycolysis. Starting from a literature-guided baseline, BO used LLM-derived semantic embeddings of chemical knowledge to navigate a high-dimensional space of 11,160 candidate pairs, identifying promising candidates beyond the initial state of the art.…

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