Tailoring Crosslinks through Time─A Paradigm for Tough Hydrogels

, spatial structure-function relationships, with particular regard to strength and toughness. While this approach has driven fundamental advancements in the design of robust hydrogel structures, further complementary perspectives are needed to enable holistic, rational design schemes that integrate considerations such as fabrication and advanced functions like response and adaptation. To these ends, this review focuses on the dynamics of temporal-function relationships and their fundamental bases in order to highlight how the dynamic regulation of polymer interactions programs: 1) polymer assembly and material structure; 2) response to deformation and fracture behavior; 3) dynamic modulation of properties and…

• BU
  Brown University
• AC
  American Chemical Society Petroleum Research Fund

  Award: 66525-DNI7
• DO
  Division of Civil, Mechanical and Manufacturing Innovation

  Awards: 2334664, 2334663
• BE
  Basic Energy Sciences

  Award: DE-SC0025354