In Situ Reformatsky Reaction‐Induced Surface Polymerization Toward an Oriented Monomeric Structure for Superior Zinc Anode Stability
Shanghai University · Shanghai University of Engineering Science · +1 more institution
Abstract
ABSTRACT Addressing the intrinsic heterogeneity of zinc anodes, which triggers dendritic growth and parasitic reactions, is paramount for realizing safe and durable zinc‐ion batteries. The homogenization of in situ active sites and deposition serves as a critical approach to suppress dendrite growth. Herein, this work adopts an in situ Reformatsky reaction capable of eliminating active sites on the Zn surface while simultaneously generating a zincophilic metal‐organic polymer framework. This mechanism not only provides uniform ion channels but also promotes uniform zinc deposition by increasing the density of nucleation sites, ultimately inducing the preferential growth of thermodynamically stable (002)…
Citation impact
- FWCI
- 52.51
- Percentile
- 100%
- References
- 43
Authors
7- YHYiyang Hu
Shanghai University, Shanghai University of Engineering Science, State Key Laboratory of Chemical Engineering
- LCLing Chen
Shanghai University, Shanghai University of Engineering Science, State Key Laboratory of Chemical Engineering
- WDWei Ding
Shanghai University, Shanghai University of Engineering Science, State Key Laboratory of Chemical Engineering
- YWYibo Wu
Shanghai University, Shanghai University of Engineering Science, State Key Laboratory of Chemical Engineering
- BTBozhong Tian
Shanghai University, Shanghai University of Engineering Science, State Key Laboratory of Chemical Engineering
Topics & keywords
- Zinc
- Nucleation
- Anode
- Monomer
- Current density
- Polymer
- In situ
- Polymerization