articleACS Sustainable Chemistry & EngineeringFeb 11, 2026Closed access

Biomass-Derived Carbon Modified with Conductive Co 3 (HHTP) 2 Nanorods as an Efficient Binder-Free Cathode for High-Performance Li–CO 2 Batteries

Jiangsu University · Division of Materials Science and Engineering · +1 more institution

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Abstract

Lithium–CO2 (Li–CO2) batteries have become an attractive research focus because of their exceptional theoretical energy density and their capability to convert and utilize carbon dioxide. Nevertheless, their practical development is impeded by the poor electrical conductivity of the resulting Li2CO3 discharge products, significant charge–discharge polarization, and sluggish CO2 reduction/evolution kinetics. This study presents the uniform anchoring of one-dimensional electrically conductive metal–organic framework (Co3(HHTP)2) nanorods onto a carbon wood (CW) membrane, derived from Balsa wood, via a hydrothermal process, resulting in the formation of a Co3(HHTP)2@CW composite cathode. The free-standing…

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