Molecular solar thermal energy storage in Dewar pyrimidone beyond 1.6 megajoules per kilogram
University of California, Santa Barbara · Brandeis University · +1 more institution
Abstract
Storing sunlight in a compact and rechargeable form remains a central challenge for solar energy utilization. Molecular solar thermal (MOST) energy storage systems, which harness photon energy and release it as heat on demand, provide a direct approach but have long failed to meet practical benchmarks. Inspired by the architecture of DNA, we report a pyrimidone-based MOST system that stores energy in the strained Dewar photoisomer upon excitation at 300 nanometers. Designed with sustainability in mind, the system operates solvent free and remains compatible with aqueous environments while overcoming one of the field's greatest hurdles-the controlled extraction and transfer of stored heat. When catalyzed by…
Citation impact
- FWCI
- 52.51
- Percentile
- 100%
- References
- 133
Authors
12- HPHan P. Q. NguyenCorresponding
University of California, Santa Barbara, Brandeis University
- AJAlexander J. Maertens
University of California, Los Angeles
- BABenjamin A. Baker
University of California, Santa Barbara, Brandeis University
- NMNathan M.-W. Wu
Brandeis University
- ZYZihao Ye
University of California, Los Angeles
Topics & keywords
- Thermal energy storage
- Solar energy
- Thermal energy
- Energy storage
- Thermal
- Energy (signal processing)
- Heat transfer
- Chemical energy
Funding
- NSNational Science FoundationAwards: DMR-2011846, DGE-2034835, CHE-215372, DMR-2142887
- APAlfred P. Sloan FoundationAward: FG-2022-18328
- GAGordon and Betty Moore FoundationAward: GBMF13626
- AAAmerican Association for the Advancement of Science
- CACamille and Henry Dreyfus FoundationAward: TC-23-028
- RCResearch Corporation for Scientific AdvancementAward: SA-SM3-2024-057b